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www.epa.gov/airnow/
National Program

The Office of Air and Radiation (OAR) develops national programs, technical policies, and regulations for controlling air pollution and radiation exposure. OAR is concerned with energy conservation and pollution prevention, indoor and outdoor air quality, industrial air pollution, pollution from vehicles and engines, radon, acid rain, stratospheric ozone depletion, and radiation protection.

Be sure to check out their basic Info page and the Plain English Guide to the Clean Air Act.